Cyclodextrin-modified MEKC for enantioseparation of hexaconazole, penconazole, and myclobutanil

Publons ID4140065
Wos IDWOS:000263385600019
Doi10.1002/jssc.200800512
TitleCyclodextrin-modified MEKC for enantioseparation of hexaconazole, penconazole, and myclobutanil
First Author
Last Author
AuthorsIbrahim, WAW; Hermawan, D; Sanagi, MM; Aboul-Enein, HY;
Publish DateFEB 2009
Journal NameJOURNAL OF SEPARATION SCIENCE
Citation16
AbstractA CD-modified micellar EKC (CD-MEKC) method with 2-hydroxypropyl-gamma-CD (HP-gamma-CD) as chiral selector for the enantioseparation of three chiral triazole fungicides, namely hexaconazole, penconazole, and myclobutanil, is reported for the first time. Simultaneous enantioseparation of the three triazole fungicides was successfully achieved using a CD-MEKC system containing 40 mM HP-gamma-CD and 50 mM SDS in 25 mM phosphate buffer (pH 3.0) solution with resolutions (R,) greater than 1.60, peak efficiencies (N) greater than 200000 for all enantiomers and an analysis time within 15 min compared to 36 min as previously reported using sulfated-beta-CD.
Publish TypeJournal
Publish Year2009
Page Begin466
Page End471
Issn1615-9306
Eissn1615-9314
Urlhttps://www.webofscience.com/wos/woscc/full-record/WOS:000263385600019
AuthorDADAN HERMAWAN
File55693.pdf